10.1002/adsc.202000267
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added. The bottle equipped with a graphite rod ( = 6
mm) as the anode and platinum electrode (1.0 cm × 1.0 cm
× 0.2 mm) as the cathode was then charged with nitrogen.
Under the protection of N2, CH3CN (16 mL) was injected
into the tubes via syringes. The reaction mixture was
stirred and electrolyzed at a constant current of 12 mA at
70 °C for 7-10 h. When the reaction was finished, the
reaction mixture was washed with water and extracted
with diethyl ether (10 mL × 3). The organic layers were
combined, dried over Na2SO4, and concentrated. The pure
product was obtained by flash column chromatography on
silica gel.
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Acknowledgments
This work was supported by the National Natural Science
Foundation of China (Nos. 11972195, 11702141 and
21771108).
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7
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