Russian Chemical Bulletin p. 2429 - 2433 (1998)
Update date:2022-08-05
Topics:
Avetisyan
Cherstkov
Tumanskii
Sterlin
The addition of peroxydisulfuryl difluoride (FSO3)2 to isomeric perfluoroisononenes (perfluoropropylene trimers) was studied. Isomers containing the trisubstituted C=C bond form adducts which were converted to the corresponding ketofluorosulfates under the action of weak nucleophiles (DMF and AcONa/AcOH) and underwent haloform-type decomposition under the action of CsF to form perfluoroalkenyl fluorosulfates and products of their subsequent conversions.
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