
Journal of the Chemical Society. Perkin transactions I p. 251 - 255 (1981)
Update date:2022-09-26
Topics:
Fleming, Ian
Pearce, Andrew
The allylsilane, 6,6-dimethoxy-2-(trimethylsilylmethyl)hex-1-ene (2) gives 3-methylenecyclohexyl methyl ether (7) on treatment with tin (IV) chloride, whereas cyclisation of the corresponding compound without the silyl group (1) was known to give five products (5)-(6).The synthesis of the allylsilane (2) is described.
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