Transannular Cyclization of a trans-1(10)-cis-4-Germacradiene

DOI: 10.1021/jo00326a011

Source and publish data:

Journal of Organic Chemistry p. 2665 - 2667 (1981)

Update date:2022-08-05

Topics:

Authors:

Williams, John R.

Callahan, James F.

Blount, John F.

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Article abstract of DOI:10.1021/jo00326a011

New biomimetic cyclization of the trans-1(10)-cis-4-germacradiene 4a by using acetic acid in thiophenol afforded the cadinane 5 and the eudesmanes 6a, b and 7.The structure of each product was determined by spectral analysis, and the absolute configuration of 7 was determined by X-ray crystallography.

Full text of DOI:10.1021/jo00326a011

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