Journal of Organic Chemistry p. 2665 - 2667 (1981)
Update date:2022-08-05
Topics:
Williams, John R.
Callahan, James F.
Blount, John F.
New biomimetic cyclization of the trans-1(10)-cis-4-germacradiene 4a by using acetic acid in thiophenol afforded the cadinane 5 and the eudesmanes 6a, b and 7.The structure of each product was determined by spectral analysis, and the absolute configuration of 7 was determined by X-ray crystallography.
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