Tetrahedron p. 3559 - 3562 (1980)
Update date:2022-09-26
Topics:
Giordano, Claudio
Belli, Aldo
Citterio, Attilio
Minisci, Francesco
A new synthesis of γ-lactones by peroxydisulfate oxidation of isopropylbenzenes is described.Evidence concerning the free-radical mechanism is reported; the intermediate formation of alkyl and benzyl radicals is evidenced by trapping them with quinoxaline.The role of the iron catalyst is discussed.
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(1981)
