Journal of the Chemical Society. Chemical communications p. 1164 - 1166 (1983)
Update date:2022-08-03
Topics:
Horton, Derek
Machinami, Tomoya
Takagi, Yasushi
Bergmann, Carl W.
Christoph, Gary C.
Acyclic unsaturated sugars obtained by Wittig extension of aldehydo arabinose precursors undergo stereoselective Diels-Alder addition of cyclopentadiene, permitting isolation of a single, crystalline, optically pure norbornene adduct whose stereochemistry may be controlled by the enantiomeric form of the sugar used and the conditions of the cycloaddition reaction.
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