Observation of Periselectivity for the Cyclocoupling Reactions of 2-Oxyallyl Cation with Tricarbonyliron Complexes of Seven-Membered-Ring Unsaturated Compounds

DOI: 10.1021/jo00331a009

Source and publish data:

Journal of Organic Chemistry p. 3630 - 3634 (1981)

Update date:2022-08-05

Topics:

Authors:

Ishizu, Takashi

Harano, Kazunobu

Yasuda, Masami

Kanematsu, Ken

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00331a009

The 2-oxyallyl cation (2) showed significant differences of periselectivity in reactions between seven-membered-ring unsaturated compounds with masking and without masking by tricarbonyliron.The cation 2 reacted with tricarbonyl(cycloheptatriene)iron (3)

Full text of DOI:10.1021/jo00331a009

Products guided by the article

Product name:1-(4-Chloro-phenyl)-2,2,4,4-tetramethyl-1,2,4,9-tetrahydro-cyclohepta[b]pyridin-3-one

Cas No:78109-53-2

R&D Labs maybe for 78109-53-2

Xi'an Tizan Tech & Industry Co., Ltd.

Contact:86-18629066522

Address:C3009 TANG FENG INTERNATIONAL PLAZA, NO.18 FENGHUI NAN ROAD, XI'AN HIGH TECH ZONE, 710075 CHINA.
Du-Hope International Group

website:http://www.np-chem.com

Contact:0086-25-52346877

Address:199, Jian Ye Road, Nanjing, China
SHENYANG COMEBOARD TECHNOLOGY CO., LTD

Contact:+86-24-25724626

Address:Room2210,Tianbao International Building,No.8-1 Weigong South Street,Tiexi District,Shenyang,China
Baoding City Light Industry And Textiles Imp.& Exp. Corp. Chemical Department.

Contact:86-312-3262436

Address:NO.658 CHAOYANG SOUTH STREET,BAODING CITY HEBEI CHINA
SuZhou Bichal Biological Technology CO.,LTD

Contact:+86-512-68051130

Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China

Relevant to this article

Design, synthesis, and biological evaluation of new 6,: N ²-diaryl-1,3,5-triazine-2,4-diamines as anticancer agents selectively targeting triple negative breast cancer cells

Doi:10.1039/d0ra04970k
(2020)
A highly efficient, preorganized macrobicyclic receptor for halides based on CH... and NH...anion interactions

Doi:10.1021/ja047070g
(2004)
Doi:10.1021/ja01119a054
(1953)
Doi:10.1039/jr9410000487
(1941)
Synthesis and anticonvulsant activity of some 1,2,3,3α-tetrahydropyrrolo[2,1-b]-benzothiazol-, -thiazol- or -oxazol-1-ones in rodents

Doi:10.1111/j.2042-7158.1996.tb03984.x
(1996)
Study of the heterocyclization of vic-substituted hydrazides of acetylenylpyrazolecarboxylic acids into N-amino pyrazolopyridinones

Doi:10.1002/jhet.5570390617
(2002)

Article Doi