Journal of the Chemical Society. Perkin transactions I p. 1421 - 1423 (1981)
Update date:2022-08-04
Topics:
Fleming, Ian
Langley, Jennifer A.
The protodesilylation of either 1-dimethyl(phenyl)silyl-3-trimethylsilylpropene (15) or its isomer, 1-trimethylsilyl-3-dimethyl(phenyl)silylpropene (16), gave the same, 4:1, mixture of allylsilanes, 3-dimethyl(phenyl)silylpropene (18) and 3-trimethylsilylpropene (19), showing that a cationic intermediate (17) is involved in both reactions.
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