Journal of the Chemical Society. Perkin transactions I p. 1577 - 1581 (1981)
Update date:2022-08-04
Topics:
Tamura, Yasumitsu
Kawasaki, Tomomi
Yasuda, Hitoshi
Gohda, Noriko
Kita, Yasuyuki
A number of epoxides smoothly react with TPPT under mild conditions to give α-thiocyanatovinyl ketones, vic-dithiocyanates, or vic-thiocyanatohydrins, depending on the structures of the epoxides used.The reactions proceed site- and stereo-specifically, to give α-thiocyanatovinyl ketones from αβ-epoxyketones, threo-dithiocyanate from trans-epoxide, erythro-dithiocyanate from cis-epoxide, and vic-thiocyanatohydrins from 1,1-disubstituted or fused epoxides, respectively.A possible mechanism for these reactions is put forward.
View MoreContact:86-516-66656369
Address:The west road of Huaihai, Xuzhou, China
Zibo Fuxi'er Chemical Co.,Ltd （Shanxian Fuxi'er Chemical Co.,Ltd）
Contact:+86-533-2091422
Address:Eastern 4 on the 3th Road ,Liangxiang Industrial Park, Zibo city ,Shandong,China
Yicheng Goto Pharmaceuticals Co.,Ltd.
Contact:+86 710 3423122
Address:5th Floor,East Gate of Building #2,Servo-Industrial Park,1st Qilin Road,Xiangyang,Hubei,China
Yangzhou Zhongbao Pharmaceutical Co.,Ltd
Contact:+86-514-88290838
Address:Jiangsu Baoying county economic develpment zone in baoying avenue91
Suzhou Ryan Pharmachem Technology Co.,Ltd
Contact:+86-0512-68780025
Address:B-301,No.2 Taishan Road,Suzhou New District,Jiangsu,P.R. China
Doi:10.1007/BF00949722
(1981)Doi:10.1016/S0040-4039(00)74720-4
(1992)Doi:10.1021/jo00156a018
(1983)Doi:10.1016/S0040-4020(01)88450-7
(1984)Doi:10.1016/j.steroids.2005.04.008
(2005)Doi:10.1021/jo005602f
(2000)
