Partially Fluorinated Heterocyclic Compounds. Part 14. Syntheses of 4,5,6,7-Tetrafluoro-2,3-dihydro-2-methyl-1-benzothiophen and 5,6,7,8-Tetrafluorothiochroman from Pentafluorophenyl Prop-2-enyl Sulphide via the Claisen Rearrangement Intermediate and the

DOI: 10.1039/P19810001659

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1659 - 1664 (1981)

Update date:2022-08-05

Topics:

Authors:

Brooke, Gerald M.

Wallis, Derek I.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19810001659

Prop-2-enyl 2,3,4,5-tetrafluorophenyl sulphide (1) undergoes a Claisen rearrangement in NN-diethylaniline to give 4,5,6,7-tetrafluoro-2,3-dihydro-2-methyl-1-benzothiophen (4) and 5,6,7,8-tetrafluorothiochroman (5).Pentafluorophenyl prop-2-enyl sulphide (3

Full text of DOI:10.1039/P19810001659

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:5,7,8-trifluorothiochroman

Cas No:78522-93-7

R&D Labs maybe for 78522-93-7

Shanghai Pengkai Chemical Co.,Ltd

Contact:+86-21-60526671

Address:No.4226 Duzhuang Rd Minhang District Shanghai China
Huaian Double Win Chemicals Co.,Ltd.

Contact:+86-13511538872

Address:Blk 43,Greenland Century Town,Huaian District, Huaian City,Jiangsu Province,China
Jiangsu Seed Chem Co.,Ltd.

Contact:86-513-84128750/13773795976

Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China
Jiangsu Wanlong Chemical Co., Ltd.

website:http://www.wanlongchem.com

Contact:+86-511-86810993 0086-511-8681 0888;

Address:Quanzhou Town, Danyang City, Jiangsu
Zhenjiang Haitong Chemical Industry Co., Ltd.

Contact:+86 (511) 8448-0369

Address:Baoyan Town, Dantu District, Zhenjiang City, Jiangsu, China

Relevant to this article

Doi:10.1002/hlca.19520350514
(1952)
Vapour-assisted enzymatic hydrolysis of β-lactams in a solvent-free system

Doi:10.1016/j.tetasy.2008.04.003
(2008)
Covalent Nucleoside Adducts of Benzo pyrene 7,8-Diol 9,10-Epoxides: Structural Reinvestigation and Characterization of a Novel Adenosine Adduct on the Ribose Moiety.

Doi:10.1021/jo00001a007
(1991)
Footprint Catalysis. VI. Chiral "Molecular Footprint" Catalytic Cavities Imprinted by a Chiral Template, Bis(N-benzyloxycarbonyl-L-alanyl)amine, and Their Stereoselctive Catalyses

Doi:10.1246/bcsj.66.906
(1993)
SYNTHESIS OF NATURAL POLYENE ISOBUTYLAMIDES. STEREOCHEMISTRY OF THE WITTIG REACTIONS

Doi:10.1016/S0040-4039(00)94859-7
(1985)
CO and O₂ binding to pseudo-tetradentate ligand-copper(I) complexes with a variable N-donor moiety: Kinetic/thermodynamic investigation reveals ligand-induced changes in reaction mechanism

Doi:10.1021/ja104107q
(2010)

Article Doi