Asymmetric Induction in the Reaction of β-Oxosulphoximides by Sodium Borohydride

DOI: 10.1039/P19810001109

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 1109 - 1111 (1981)

Update date:2022-08-05

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Authors:

Annunziata, Rita

Cinquini, Mauro

Cozzi, Franco

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Article abstract of DOI:10.1039/P19810001109

Optically active β-oxosulphoximides have been prepared by reaction of optically active α-metallated NS-dimethyl-S-phenylsulphoximide with carboxylic esters.Their reduction by sodium borohydride is stereoselective, the extent of asymmetric synthesis (up to

Full text of DOI:10.1039/P19810001109

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