Journal of Organometallic Chemistry p. 311 - 323 (1981)
Update date:2022-08-05
Topics:
Manuel, Georges
Bertrand, Guy
Mazerolles, Pierre
Ancelle, Jacques
The thermolysis of linear and cyclic β-chloro-β'-ethylenesilicon compounds gives rise to two competitive reactions.Besides the classical β-elimination reaction, a new rearrangement reaction was observed, which depends on the Si-bonded R groups; it has not been noticed for the corresponding germanium compounds.To explain the results, we propose a mechanism involving a transient pentavalent silicon anion.
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Doi:10.1016/S0022-328X(00)81910-5
(1981)Doi:10.1055/s-2004-829186
(2004)Doi:10.1016/j.bmcl.2013.08.049
(2013)Doi:10.1021/jo01082a008
(1960)Doi:10.1016/S0223-5234(03)00144-2
(2003)Doi:10.1246/bcsj.31.351
(1958)
