Journal of Organic Chemistry p. 3901 - 3903 (1981)
Update date:2022-09-26
Topics:
Byon, Chang-Yon
Gut, Marcel
Toome, Voldemar
The stereospecific synthesis of (25S)-26-hydroxycholesterol with a chiral synthon derived from (S)-(+)-3-hydroxy-2-methylpropanoic acid is described and the Cotton effects of the CD spectra were found not to be a general means for distinguishing epimers of monohydric secondary alcohols or for distinguishing epimers in which the chiral center is in the α position to the primary alcoholic function.
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