Synthesis and Reactivity of a Monomeric 14-Electron 'Bare' Ruthenium(II) Porphyrin Complex; Reversible Binding of Dinitrogen to form Mono- and Bis-dinitrogen Complexes

DOI: 10.1039/c39860001137

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1137 - 1139 (1986)

Update date:2022-08-05

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Authors:

Camenzind, Mark J.

James, Brian R.

Dolphin, David

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Article abstract of DOI:10.1039/c39860001137

The 14-electron species Ru(TMP), obtained via vacuum pyrolysis of Ru(TMP)(MeCN)2, reacts with a plethora of ligands to form bis-ligated species, including the first bis(dinitrogen) metalloporphyrin complex .

Full text of DOI:10.1039/c39860001137

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