STEREOSELECTIVE ADDITION OF READILY AVAILABLE ORGANOCOPPER REAGENTS TO DIMETHYL ACETYLENEDICARBOXYLATE

DOI: 10.1246/cl.1981.905

Source and publish data:

Chemistry Letters p. 905 - 908 (1981)

Update date:2022-08-05

Topics:

Authors:

Nishiyama, Hisao

Sasaki, Masaharu

Itoh, Kenji

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Article abstract of DOI:10.1246/cl.1981.905

Organocopper reagents derived from cuprous bromide-dimethyl sulfide complex with Grignard reagents underwent stereoselective addition to dimethyl acetylenedicarboxylate to give 2-substituted maleates in good yields.

Full text of DOI:10.1246/cl.1981.905

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