SYNTHESIS OF DEHYDROXY-trans-RESORCYLIDE BY INTRAMOLECULAR ALKYLATION OF THE PROTECTED CYANOHYDRIN USING A BUTADIENE TELOMER AS A BUILDING BLOCK

DOI: 10.1016/S0040-4039(01)92961-2

Source and publish data:

Tetrahedron Letters p. 2651 - 2654 (1981)

Update date:2022-08-04

Topics:

Authors:

Takahashi, Takashi

Minami, Ichiro

Tsuji, Jiro

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Article abstract of DOI:10.1016/S0040-4039(01)92961-2

Dehydroxy-trans-resorcylide (15) was synthesized by efficient intramolecular alkylation of the protected cyanohydrin.The butadien telomer obtained by the palladium catalyzed reaction of butadiene which acetic acid was used as a suitable building block of the carbocycle.

Full text of DOI:10.1016/S0040-4039(01)92961-2

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