Alkylation of Thioureas and Related Compounds by Use of Alcohols, Diethyl Azodicarboxylate, and Triphenylphosphine

DOI: 10.1246/bcsj.54.2223

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2223 - 2224 (1981)

Update date:2022-09-26

Topics: Alkylation Nucleophile Triphenylphosphine Organic synthesis alcohol Thioureas Diethyl Azodicarboxylate

Authors:

Nagasawa, Hiroshi

Mitsunobu, Oyo

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Article abstract of DOI:10.1246/bcsj.54.2223

The alkylation of ambident nucleophiles having a thiocarbonyl group by use of alcohols, diethyl azodicarboxylate, and triphenylphosphine was studied.Selective S-alkylation took place in the cases of N-benzoyl-N'-mono- and -disubstituted thioureas, while s

Full text of DOI:10.1246/bcsj.54.2223

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