Alkylation of Thioureas and Related Compounds by Use of Alcohols, Diethyl Azodicarboxylate, and Triphenylphosphine

DOI: 10.1246/bcsj.54.2223

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2223 - 2224 (1981)

Update date:2022-09-26

Topics: Alkylation Nucleophile Triphenylphosphine Organic synthesis alcohol Thioureas Diethyl Azodicarboxylate

Authors:

Nagasawa, Hiroshi

Mitsunobu, Oyo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.54.2223

The alkylation of ambident nucleophiles having a thiocarbonyl group by use of alcohols, diethyl azodicarboxylate, and triphenylphosphine was studied.Selective S-alkylation took place in the cases of N-benzoyl-N'-mono- and -disubstituted thioureas, while s

Full text of DOI:10.1246/bcsj.54.2223

Products guided by the article

Product name:1-Methoxymethyl-3-phenethyl-2-thioxo-2,3-dihydro-1H-pyrimidin-4-one

Cas No:79564-13-9

R&D Labs maybe for 79564-13-9

Shanghai Yudiao Chemistry Technology Co.,Ltd

Contact:0086-18964703211

Address:Building NO.5, NO.218,Rongtian Road,ganxiang town,Jinshan District,shanghai,201518,china
Chengdu Baishixing Science and Technology Industry Co., Ltd.

website:http://www.cd-bsx.com

Contact:+86-28-88531548

Address:#217,North of Industry Road,Heshan Town,Pujiang County,Chengdu,Sichuan,China.
Yicheng Goto Pharmaceuticals Co.,Ltd.

Contact:+86 710 3423122

Address:5th Floor,East Gate of Building #2,Servo-Industrial Park,1st Qilin Road,Xiangyang,Hubei,China
Huludao Tianqi Shengye Chemical Co.,Ltd.

Contact:0086 429 2075777

Address:Area B,Shipbuilding Industry Park,Beigang District,Huludao City,Liaoning prov.,China
KindChem Co.,Ltd,

Contact:+86-25-85281586

Address:13F,Bld2#,South of Longpan Road

Relevant to this article

Phosphoric Amides. 5. Acid-Catalyzed Hydrolysis of Dimethyl N-(Alkylphenyl)phosphoramidates

Doi:10.1021/jo00138a002
(1982)
Stereodivergent construction of cyclic ethers by a regioselective and enantiospecific rhodium-catalyzed allylic etherification: Total synthesis of gaur acid

Doi:10.1002/anie.200460612
(2004)
Efficient and Selective Methane Borylation Through Pore Size Tuning of Hybrid Porous Organic-Polymer-Based Iridium Catalysts

Doi:10.1002/anie.201906350
(2019)
Hydrosilylation of carbonyl and carboxyl groups catalysed by Mn(i) complexes bearing triazole ligands

Doi:10.1039/c9cy01738k
(2019)
Periselective Cycloaddition of Tricarbonyliron Complexes of Seven-Membered Unsaturated Compouds with 1,2,4,5-Tetrazine. Masking and Activating Effects of Tricarbonyliron Complexes

Doi:10.1021/jo00340a024
(1982)
Amide linkage isomerism as an activity switch for organometallic osmium and ruthenium anticancer complexes

Doi:10.1021/jm900731j
(2009)

Article Doi