Reaction of a Silyl-Copper Reagent with Acetylenes: a New Synthesis of Vinylsilanes

DOI: 10.1039/c39800000276

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 276 - 277 (1980)

Update date:2022-08-03

Topics: Workup

Authors:

Fleming, Ian

Roessler, Felix

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Article abstract of DOI:10.1039/c39800000276

A silyl-cuprate reagent adds regioselectively to terminal acetylenes and the intermediate (3) reacts with electrophiles to give 2,2-disubstituted vinylsilanes.

Full text of DOI:10.1039/c39800000276

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