UEBERGANGSMETALL-SUBSTITUIERTE PHOSPHANE, ARSANE UND STIBANE. XXVIII. UEBERGANGSMETALL-DIPHENYLPHOSPHANE VON MOLYBDAEN UND WOLFRAM; DARSTELLUNG, REAKTIONEN UND NMR-SPEKTROSKOPISCHE CHARAKTERISIERUNG

DOI: 10.1016/S0022-328X(00)83110-1

Source and publish data:

Journal of Organometallic Chemistry p. C1 - C6 (1981)

Update date:2022-08-03

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Authors:

Malisch, Wolfgang

Maisch, Roman

Colquhoun, Ian J.

McFarlane, William

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Article abstract of DOI:10.1016/S0022-328X(00)83110-1

Na (M = Mo, W) and Ph2PCl react to give the transition metal substituted phosphanes Cp(CO)3MPPh2 (I, II), which are transformed to trans-Cp(CO)2PMe3MPPh2 (III, IV) via CO/PMe3-exchange.The high nucleophilicity of the phosphanes I-IV is demonstra

Full text of DOI:10.1016/S0022-328X(00)83110-1

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