Journal of the American Chemical Society p. 1421 - 1426 (1984)
Update date:2022-07-30
Topics: Chiral center Enantiomers Diastereomers Dynamic NMR Racemization Interconversion Transition state Arrhenius equation Optical activity Thermal stereomutations Rate Constant (k) Eyring Plot Activation energy (Ea) Half-life (t?/?) Conformational isomerism
Baldwin, John E.
Patapoff, Thomas W.
Barden, Timothy C.
All three achiral forms of 1-phenyl-1,2,3-trideuteriocyclopropane have been synthesized with high stereochemical integrity, and the thermal stereomutations among them have been followed at 309.3 deg C in the gas phase by Raman and 1H NMR spectroscopy.The
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