Chemistry Letters p. 79 - 80 (1982)
Update date:2022-08-04
Topics:
Ochiai, Masahito
Sumi, Kenzo
Fujita, Eiichi
Cyclopropyl ketones 2 were smoothly cleaved with boron trifluoride-acetic acid under mild reaction conditions by the assistance of trimethylsilyl group to give γ,δ-enones in good yields and the reaction was applied to the formal total synthesis of cis-jasmone.
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Doi:10.1016/S0008-6215(00)80791-0
(1982)Doi:10.1081/SCC-200034770
(2004)Doi:10.1038/s41429-019-0199-3
(2019)Doi:10.1021/jp971310f
(1997)Doi:10.1039/P19810003074
(1981)Doi:10.1016/j.tetasy.2004.09.010
(2004)