aSYNTHESIS AND STRUCTURE OF NEUTRAL AND CATIONIC PENTAHALOARYLPALLADIUM(II) ISONITRILE COMPLEXES

Article abstract of DOI:10.1016/S0022-328X(00)82291-3

Complexes of the types (a) trans- and cis-, (b) trans- and (c) ClO4 (X=F or Cl; R=Bu-t, cyclohexyl or p-tolyl) have been made by replacement of the tetrahydrothiophen or Cl groups of appropriate precursors by isonitrile.Their structures have been assigned on the basis of their IR and 1H NMR spectra.