Occurrence of Even Telesubstitution in the Amination of Halogeno-2,6-naphthyridines

DOI: 10.1021/jo00348a012

Source and publish data:

Journal of Organic Chemistry p. 1673 - 1677 (1982)

Update date:2022-08-04

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Authors:

Haak, Henk J. W. van den

Plas, Henk C. van der

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Article abstract of DOI:10.1021/jo00348a012

The conversion of 1-halogeno-2,6-naphthyridines into 1-amino-2,6-naphthyridine is shown to proceed via an even telesubstitution process N(AE)^tele process>.The amination of 2-bromo-1,5-naphthyridine into 2-amino-1,5-naphthyridine is shown to proceed via an S_N(AE)^ipso substitution mechanism.

Full text of DOI:10.1021/jo00348a012

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