Journal of the Chemical Society. Perkin transactions I p. 3114 - 3117 (1981)
Update date:2022-08-05
Topics:
Sako, Magiochi
Suzuki, Mikio
Tanabe, Miyuki
Maki, Yoshifumi
Thermolysis of various 5-bromouracils (1) in N,N-dialkylamides results in the formation of methylenebisuracils (2) and reductive debrominated products (3) via cleavage of the C(5)-Br bond; the latter involves a one-electron transfer process.The product distribution between (2) and (3) depends upon the nature of substituents in the uracil ring.
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