Journal of the Chemical Society. Perkin transactions I p. 3002 - 3007 (1981)
Update date:2022-08-03
Topics:
Parr, William J. E.
The synthesis of novel N,N'-substituted para-phenylenediamines bearing side-chains containing one or two monoselenide linkages is described.Reductive alkylation of para-phenylenediamines with oxoselenides using sodium cyanoborohydride in methanol gives good to high yields of these compounds.Compounds containing one selenide linkage react with 3 mol equivalents of ozone, and those containing two selenide linkages react with 4 mol equivalents of ozone, compared to only 2 mol equivalents of ozone in the case of N-isopropyl-N'-phenyl-p-phenylenediamine.Synthetic routes to the oxoselenides required as precursors are described.
View MoreContact:0027-717-456976
Address:2ND FLOOR, 325 VAUSE ROAD, OVERPORT, 4001, SOUTH AFRICA
Hangzhou Ocean Chemical Co., Ltd.
website:http://www.hzoceanchem.com
Contact:+86-571-88025872, 28272092, 28272096
Address:Room 623 ,Building No 1 , COFCO Radius Commercial Center Xiwen Road, Xiacheng District, Hangzhou, Zhejiang Province, China
Contact:+86-22-83718541
Address:32th Floor, Rongqiao Center Intersection of Changjiang Road and Nankai Six Road Nankai District Tianjin 300102, China
Anhui Redstar Pharmaceutical Corp., Ltd
Contact:+86-563-5120837
Address:Jingxian Industrial Development Zone, Anhui , China
Shanghai He Yang International Trading Co., Ltd.
Contact:+86-21-52043598
Address:Room 816, Blag.5, No.58 Huachi Road
Doi:10.1246/cl.1983.1051
(1983)Doi:10.1016/S0040-4039(01)83009-4
(1981)Doi:10.1007/BF00513296
(1982)Doi:10.1021/acs.jnatprod.6b01119
(2017)Doi:10.1021/ol0481939
(2004)Doi:10.1021/ja00161a052
(1990)
