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Synthesis and Reactivity of Bimetallic Au-Ag Complexes. X-Ray Structure of a Chain Polymer containing the Moiety ...(F5C6)2Au(μ-AgSC4H8)2Au(C6F5)2...

DOI: 10.1039/c39810001097

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1097 - 1098 (1981)

Update date:2022-08-04

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Authors:

Uson, RafaelUson, Rafael

Laguna, AntonioLaguna, Antonio

Laguna, MarianoLaguna, Mariano

Jones, Peter G.Jones, Peter G.

Sheldrick, George M.Sheldrick, George M.

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Article abstract of DOI:10.1039/c39810001097

The 1 : 1 reaction between and AgClO4 in dichloromethane gives yellow solutions, from which solids of stoicheiometry Au(C6F5)AgL can be precipitated by the addition of O, N, S, or P-donors, L; an X-ray diffraction study for L = SC4H8 reveals 2 rings linked by Au ...Au interactions to form infinite metal-atom chains.

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Product name:Ag(P(C6H5)2CH3)2(1+)*Au(C6F5)2(1-)=Ag(P(C6H5)2CH3)2Au(C6F5)2

Cas No:81368-71-0

81368-71-0

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