A Novel Synthetic Approach to the Ecdysone Side-chain via Furan Derivatives

DOI: 10.1039/P19810003077

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 3077 - 3082 (1981)

Update date:2022-08-05

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Authors:

Kametani, Tetsuji

Tsubuki, Massayoshi

Nemoto, Hideo

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Article abstract of DOI:10.1039/P19810003077

A new synthesis of (22R)-22,25-dihydroxycholesterol (6) and its 6-oxo-derivative (18) from pregnenolone via the stereoselective hydrogenation of an olefinic furan derivative (2) as a key reaction is described.

Full text of DOI:10.1039/P19810003077

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