The Shortest Synthesis of Optically Active Geissman-Waiss Lactone, A Key Synthetic Intermediate for Necine Bases

DOI: 10.1016/S0957-4166(00)82169-2

Source and publish data:

Tetrahedron Asymmetry p. 445 - 448 (1991)

Update date:2022-08-04

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Authors:

Takahata, Hiroki

Banba, Yasunori

Momose, Takefumi

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Article abstract of DOI:10.1016/S0957-4166(00)82169-2

A short synthesis of (+)-(1R,5R)-2-oxa-6-azabicyclo<3.3.0>octan-3-one (the Geissman-Waiss lactone, 1) by palladium (II)-catalyzed intramolecular aminocarbonylation of (R)-N-benzyloxycarbonyl-3-hydroxy-4-pentenylamine (4) available from the Katsuki-Sharple

Full text of DOI:10.1016/S0957-4166(00)82169-2

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