New Synthesis of Cyclopropanes from 1,3-Dicarbonyl Compounds Utilizing Electroreduction of 1,3-Dimethanesulfonates

DOI: 10.1021/jo00137a012

Source and publish data:

Journal of Organic Chemistry p. 3090 - 3094 (1982)

Update date:2022-08-02

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Authors:

Shono, Tatsuyo

Matsumura, Yoshihiro

Tsubata, Kenji

Sugihara, Yoshihiro

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Article abstract of DOI:10.1021/jo00137a012

Electroorganic synthesis of cyclopropanes from dimethanesulfonates of 1,3-diols is described.The process involves reduction of 1,3-dicarbonyl compounds with LiAlH followed by esterification with methanesulfonyl chloride and electroreduction.

Full text of DOI:10.1021/jo00137a012

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