Journal of Organometallic Chemistry p. 97 - 108 (1982)
Update date:2022-08-05
Topics:
Glogowski, M. E.
Zumbulyadis, N.
Williams, J. L. R.
The UV-visible spectral shifts observed from p-dimesitylboryl-containing dyes in alcohol/sodium hydroxide solutions are caused by attack of the base on the boron atom.This attack produces the light-sensitive, tetravalent, "ate" structure.Dyes have been synthesized with 6 methyl groups ortho to the boron.These dyes are stable to base.The 11B NMR spectra of a number of dyes and model compounds containing the dimesitylborylphenyl moiety reveal evidence of adduct formation in donor solvents.No adduct formation occurs when 5 or 6 methyl groups surround the boron atom.
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Doi:10.1021/ja01622a034
(1955)Doi:10.1016/S0040-4039(01)94144-9
(1972)Doi:10.1016/0008-6215(83)84059-2
(1983)Doi:10.1016/j.molliq.2016.04.028
(2016)Doi:10.1021/jo00180a025
(1984)Doi:10.1055/s-1983-30602
(1983)
