Journal of Organic Chemistry p. 2450 - 2457 (1986)
Update date:2022-07-29
Topics:
Larock, Richard C.
Hershberger, Susan S.
Takagi, Kentaro
Mitchell, Mark A.
Vinylmercuric chlorides, Li2PdCl4, and bicyclic alkenes react to form stable, isolable adducts (1-9) in which the vinyl and PdCl groups have been added in a cis, exo fashion across the carbon-carbon double bond.Norbornadiene under the same conditions affords an endo nortricyclyl adduct 10.These compounds have been fully characterized and undergo reactions with CO-CH3OH-Et3N, NaBH4, NaOCH3-CH3OH, H2, RLi, CuCN, and Pb(OAc)4 to give methyl esters, reduced alkanes and alkenes, cross-coupled hydrocarbons, nitriles, and acetates.
View MoreBeijing Green Guardee Technology CO,.LTD
Contact:+86-10-69706062
Address:F2 BLdj,5 No.37 Chaoqian Road
Zhejiang Genebest Pharmaceutical Co.,Ltd.
Contact:0086-571-63532866
Address:No.1 Jinboshi Rd Lishan Town Fuyang City Zhejiang Province China
website:http://www.cartoonchem.com/
Contact:+86-25-58074918
Address:Room 2109, RuiHua Business Center,315 South ZhongShan Road, Nanjing 210001, China
Anhui Xinyuan Technology Co.,Ltd
Contact:0086-559-3515800
Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Wuxi Pharma-Trading Import & Export Co.,Ltd.
Contact:+86-510-82304590 82716390
Address:Room 523,Youzu Alliance Building,No.88 Renmin Zhonglu,Wuxi,Jiangsu,China
Doi:10.1021/ja01520a032
(1959)Doi:10.1021/jo801713q
(2008)Doi:10.1021/jo01083a002
(1959)Doi:10.1002/chem.202001053
(2020)Doi:10.1021/acscatal.0c03888
(2020)Doi:10.1016/j.tet.2008.09.010
(2008)
