Journal of Organic Chemistry p. 3358 - 3360 (1982)
Update date:2022-07-30
Topics:
Esmond, Robert
Fraser-Reid, Bert
Jarvis, Bruce B.
Anguidine (3b) was converted to verrucarol (3a), which in turn was selectively acylated to yield trichoverin B (2).Trichoverrin B reacts with pyridinium dichromate in dimethylformamide, via a novel oxidative ring closure, to give verrucarin J (11a) in 50 percent yield.
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