A New Synthesis of 4-Substituted Indoles via Tricarbonylarenechromium(0) Complexes

DOI: 10.1039/c39820000467

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 467 - 468 (1982)

Update date:2022-07-30

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Authors:

Nechvatal, Gordon

Widdowson, David A.

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Article abstract of DOI:10.1039/c39820000467

Tricarbonyl-(η⁶-1-tri-isopropylsilylindole)chromium(0), lithiated selectively at C-4 by n-butyl-lithium-N,N,N',N'-tetramethylethylenediamine (TMEDA), can be substituted in good yield by a range of electrophiles; the method has been used to synthesise 4-prenylindole.

Full text of DOI:10.1039/c39820000467

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