
Tetrahedron Letters p. 6503 - 6506 (1998)
Update date:2022-08-03
Topics:
Miyaoka, Hiroaki
Isaji, Yutaka
Kajiwara, Yasuhiro
Kunimune, Iyo
Yamada, Yasuji
Marine dolabellane diterpenoid claenone (1) was synthesized from D- mannitol. This synthesis involves the formation of bicyclo[2.2.1] heptane derivative 4a by sequential Michael reaction, the formation of cyclopentane derivative 9 by retro-aldol reaction
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