Journal of Organometallic Chemistry p. 137 - 146 (1982)
Update date:2022-08-02
Topics:
Castel, A.
Riviere, P.
Satge, J.
Catalytic activity of nuclophiles such as tertiary amines and diazo derivatives in the reduction of halogermanes by means of gentle reductive agents, such as R3M(IVB)-H or RCHO, has been shown.In the particular case of enolisable aldehyde, a competition between nucleophilic substitution at the metal and germanium-halogen bond reduction has been observed.Transposition of enoxygermanes formed through the substitution process, leads to β-germylaldehydes.
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