ASYMMETRIC SYNTHESIS OF OPTICALLY ACTIVE CYCLOHEXENOL DERIVATIVES VIA HIGHLY STEREOSELECTIVE REDUCTION OF (R)-3-(p-t-BUTYLPHENYLTHIO)CYCLOHEXAN-1-ONE

DOI: 10.1246/cl.1982.899

Source and publish data:

Chemistry Letters p. 899 - 902 (1982)

Update date:2022-08-04

Topics:

Authors:

Suzuki, Keisuke

Ikegawa, Akihiko

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1982.899

(R)-3-(p-t-Butylphenylthio)cyclohexan-1-one was reduced with LiAlH(OBu^t)3 to afford (1S,3R)-3-(p-t-butylphenylthio)cyclohexan-1-ol, while the same reduction with LiBH(s-Bu)3 afforded the (1R,3R) counterpart almost exclusively.Elaboration of eac

Full text of DOI:10.1246/cl.1982.899

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