Tetrahedron Letters p. 2957 - 2960 (1982)
Update date:2022-07-29
Topics: Conjugate addition Tributyltin hydride Michael addition Alkyl groups Denitration
Ono, Noboru
Miyake, Hideyoshi
Kamimura, Akio
Tsukui, Nobuo
Kaji, Aritsune
Michael addition of nitroparaffins to α,β-unsaturated sulfoxides is well effected in the presence of DBU.The nitro group in the adduct is replaced by hydrogen with Bu3SnH without influence to the sulfinyl function.The overall reactions provide an efficien
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