A MILD METHOD FOR THE CONVERSION OF PROPIOLIC ESTERS TO β-KETO ESTERS. APPLICATION TO THE FORMAL TOTAL SYNTHESIS OF (+/-)-THIENAMYCIN

DOI: 10.1016/S0040-4039(00)88437-3

Source and publish data:

Tetrahedron Letters p. 2875 - 2878 (1982)

Update date:2022-08-03

Topics:

Authors:

Shibasaki, Masakatsu

Nishida, Atsushi

Ikegami, Shiro

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Article abstract of DOI:10.1016/S0040-4039(00)88437-3

An extremely mild method for the transformation of propiolic esters to β-keto esters via thiol addition is reported, including its succesful application to the synthesis of (+/-)-thienamycin.

Full text of DOI:10.1016/S0040-4039(00)88437-3

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