A MILD METHOD FOR THE CONVERSION OF PROPIOLIC ESTERS TO β-KETO ESTERS. APPLICATION TO THE FORMAL TOTAL SYNTHESIS OF (+/-)-THIENAMYCIN

DOI: 10.1016/S0040-4039(00)88437-3

Source and publish data:

Tetrahedron Letters p. 2875 - 2878 (1982)

Update date:2022-08-03

Topics:

Authors:

Shibasaki, Masakatsu

Nishida, Atsushi

Ikegami, Shiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)88437-3

An extremely mild method for the transformation of propiolic esters to β-keto esters via thiol addition is reported, including its succesful application to the synthesis of (+/-)-thienamycin.

Full text of DOI:10.1016/S0040-4039(00)88437-3

Products guided by the article

Product name:1-<3-(trans-2-tert-butyldimethylsilyloxycyclopentyl)propynoyl>piperidine

Cas No:83651-59-6

R&D Labs maybe for 83651-59-6

Xian Lyphar Biotech Co., Ltd.

Contact:0086-29-89196322

Address:North of the Fifth Keji Road, Hi-Tech Industrial Zone, Xi'an City, Shaanxi Province, China
Hangzhou Ledun Technology Co.,Ltd.

Contact:86-571-18767088918

Address:No.6 street,XiaSha,Hangzhou,China.
Chongqing Yawei Fine Chemical Co.,Ltd

Contact:0086-23-62849407

Address:Ziyou village, Nanquan town, Banan district, Chongqing China
ShangHai Original Economy-Trade Develop Co.,Ltd.,

Contact:86-21-68552131

Address:shanghai
Huangshi Meifeng Chemical Co.,ltd.

Contact:+86-714-6516706

Address:1941-4-3#,Hubin Avenue,Huangshi,Hubei,China

Relevant to this article

Doi:10.1246/bcsj.51.3368
(1978)
Umpolung of the 5-alkyl-2-dimethylamino-1,3-dithiolium-4-thiolate mesoion and its application in the synthesis of some new tetrathiafulvalenes

Doi:10.1002/ejoc.200300672
(2004)
One-pot Suzuki/Heck sequence for the synthesis of (E)-stilbenes featuring a recyclable silica-supported palladium catalyst via a multi-component reaction in 1,3-propanediol

Doi:10.1002/adsc.201000028
(2010)
Reinvestigation of the synthetic and mechanistic aspects of Mn(III) acetate mediated oxidation of enones

Doi:10.1016/j.tet.2004.02.039
(2004)
Use of Shift Reagent with MTPA Derivatives in 19F NMR Spectroscopy IV - Determination of Enantiomeric Composition for a Variety of Secondary Cycloalkanols. A Survey

Doi:10.1002/omr.1270210609
(1983)
Convergent diversity-oriented side-chain macrocyclization scan for unprotected polypeptides

Doi:10.1039/c3ob42168f
(2014)

Article Doi