Journal of Organic Chemistry p. 481 - 486 (1983)
Update date:2022-07-30
Topics:
Charrier, Josiane
Foucaud, Andre'
Person, Herve'
Loukakou, Emile
Reactions of isocyanides with 1-phthalimidoaziridines 1,5, and 11 gave 1-phthalimidoazetidines by <1+3> cycloaddition to the azomethine ylides that are in equilibrium with the aziridines. (tert-Butylimino)azetidines and (tert-octylimino)azetidines rearranged into open-chain azadienes.Reactions of hydrazine hydrate with 1-phthalimidoazetidines did not give the corresponding N-aminoazetidines, but rather their decomposition products, nitrogen and enamino esters.
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Doi:10.1021/ja00342a080
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