NEUTRAL AND CATIONIC DICARBONYL COMPLEXES OF MANGANESE(I) WITH DIPHOSPHINES

DOI: 10.1016/S0022-328X(00)85853-2

Source and publish data:

Journal of Organometallic Chemistry p. 175 - 184 (1982)

Update date:2022-08-03

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Authors:

Carriedo, G. A.

Riera, V.

Santamaria, J.

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Article abstract of DOI:10.1016/S0022-328X(00)85853-2

The reaction of BrMn(CO)5 with dppm in refluxing toluene gives the neutral compound cis-cis-BrMn(CO)2(dppm)2 which has been shown by 31P NMR spectroscopy to have one dppm monodentate and the other bidentate.This complex reacts with TlPF6 in dichloromethan

Full text of DOI:10.1016/S0022-328X(00)85853-2

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Product name:[Mn(CO)3(((C₆H₅)2P)2CH₂)2]⁽¹⁺⁾*PF₆^(1-)=[Mn(CO)3(((C₆H₅)2P)2CH₂)2]PF₆

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