Journal of the Chemical Society. Chemical communications p. 1153 - 1154 (1982)
Update date:2022-08-04
Topics:
Barluenga, Jose
Florez, Josefa
Yus, Miguel
Very reactive organolithium compounds bearing an alkoxide function at the β-position with respect to the metal are obtained by direct metallation with lithium naphthalenide at low temperature of the corresponding lithium chlorohydrin salt; the reaction of these dianions with different electrophilic agents leads to the corresponding mono- and bi-functionalized compounds.
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