
Journal of Organic Chemistry p. 1155 - 1159 (1983)
Update date:2022-08-04
Topics:
Hoffmann, H. M. R.
Giguere, Raymond J.
Pauluth, Detlef
Hofer, Edgar
The series of 2,2,6,6-tetramethyl-1-isopropenylcyclohexenes 2-6 shows hindered rotation of the isopropenyl group, the activation barrier ΔG(excit.) varying from 12.8 to >15.7 kcal/mol.Splitting patterns and chemical shifts of the olefinic protons of the i
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