IRON CARBONYL COMPLEXES CONTAINING AN AZOMETHYNE MOIETY. I. SYNTHESIS AND X-RAY STRUCTURE OF A NOVEL ?, ?-ARENE-BRIDGED COMPLEX, μ-(o-C6H4CH2NC6H5)Fe3(CO)8

DOI: 10.1016/S0022-328X(00)98554-1

Source and publish data:

Journal of Organometallic Chemistry p. 323 - 330 (1983)

Update date:2022-08-05

Topics:

Authors:

Nametkin, N. S.

Tyurin, V. D.

Nekhaev, A. I.

Sobolev, Yu. P.

Kondrateva, M. G.

et al. et al.

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Article abstract of DOI:10.1016/S0022-328X(00)98554-1

N-(Benzylidene)aniline (BZA) reacts with Fe3(CO)12 yielding μ-(o-C6H4CH2NC6H5)Fe2(CO)6 (I), μ-(o-C6H4CH2NC6H5)Fe3(CO)8 (II) and various products from the reduction and carbonylation of BZA and its fragments.II was characterized by X-ray crystallography and proved to be the first complex prepared with a ?,?(η¹,η⁶)-bridging arene ligand.

Full text of DOI:10.1016/S0022-328X(00)98554-1

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Product name:Fe₃(CO)8(C₆H₄CH₂NC₆H₅)

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