Journal of the Chemical Society. Perkin transactions II p. 1847 - 1852 (1988)
Update date:2022-09-26
Topics:
Avila, David V.
Davies, Alwyn G.
Davison, Ian G. E.
4a-Methyl- and 4a-ethyl-1,2,3,4,4a,5,6,7-octahydronaphthalene have been subjected to singlet oxygen oxygenation, and the various hydroperoxides which are formed have been characterised.Evidence is presented that the 8aβ-alkyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-4aα-yl hydroperoxides (I; R=Me or Et) rearrange suprafacially and irreversibly in chloroform at 25 deg C to give only the 4aβ-alkyl-2,3,4,4a,5,6,7,8-octahydronaphthalen-2α-yl hydroperoxides (II).Under the same conditions, the corresponding 8aβ-alkyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-4aβ-yl hydroperoxides rearrange much more slowly.
View MoreSuzhou Tianma Specialty Chemicals Co.,Ltd
Contact:+86-512-68090577
Address:#199, Huayuan Rd, Mudu, Suzhou, Jiangsu, CHINA
Wuhan Fortuna Chemical Co.,Ltd
website:http://www.fortunachem.com
Contact:86-27-59207850
Address:Add: Room 2015, No.2 Building, Kaixin Mansion No.107 Jinqiao Avenue, Wuhan, China
Changzhou Sunsheng Chem Co., Ltd
Contact:+1-(989)-854-0648
Address:No. 28 Yinshan Rd., Xixiashu Industrial Park
Shijiazhuang Haitian Amino Acid Co., Ltd.
Contact:+86-311-88908111
Address:Shijiazhuang Hebei province,China
Hangzhou Showland Technology Co., Ltd.
Contact:86-571-88920516
Address:ROOM2118,NO.553,WENSAN ROAD,HANGZHOU,CHINA
Doi:10.1039/c39830000688
(1983)Doi:10.1021/np050091j
(2005)Doi:10.1039/c7dt01446e
(2017)Doi:10.1021/jm501590q
(2015)Doi:10.1016/j.tetasy.2005.12.009
(2006)Doi:10.1021/ic0498081
(2004)
