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The Use of (Cyclo-octadiene)(cyclo-octatriene)ruthenium(0) as the Starting Material for the Synthesis of Mono- and Poly-nuclear Rhuthenium Polyhydride Phosphine Complexes

DOI: 10.1039/c39820001388

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1388 - 1390 (1982)

Update date:2022-08-05

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Authors:

Chaudret, BrunoChaudret, Bruno

Commenges, GerardCommenges, Gerard

Poilblanc, RenePoilblanc, Rene

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Article abstract of DOI:10.1039/c39820001388

Ru(cod)(cot) (cod = 1-2:5-6-η-cyclo-octadiene; cot = 1-2:3-4:5-6-η-cyclo-octatriene) has been shown to be an efficient starting material for the synthesis of a number of ruthenium(0) and ruthenium hydride phosphine complexes; with monophosphines Ru(cod)(cot)L , the dinuclear complex (RuH4L2)2 (L = PiPr3, PtBu3), and the hexahydride complex RuH6L2 (L = Pcy3, cy = cyclohexyl) have been obtained whereas with diphosphines, the ruthenium(0) dinuclear complex Ru2(cod)2(cot)(dppm)2 (dppm = Ph2PCH2PPh2), the hydrido trinuclear complex 3, and RuH2(dppe)2 (dppe = Ph2PCH2CH2PPh2) are produced.

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