Tetrahedron Letters p. 3943 - 3946 (1985)
Update date:2022-07-30
Topics:
Reissig, Hans-Ulrich
Methyl 2-siloxycyclopropanecarboxylates rearrange smoothly and quantitatively to the corresponding silyl enol ethers (3) by addition of a catalytical amount of iodo trimethylsilane.Scope and limitation of this novel process as well as the synthesis of the electron rich diene (10a) are described.
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