Tetrahedron p. 2355 - 2363 (1982)
Update date:2022-08-04
Topics:
Torregrosa, J. L.
Baboulene, M.
Speziale, V.
Lattes, A.
The hydroboration reaction of acetylenic amines R1R2N-CH(R3)-C<*>C-R4 was studied.We report the first results of a study of the reactivity of dialkylborane R2BH towards these amines which allow us to propose a new method for the synthesis of differently substituted β-ethylenic amines.The regioselectivity and the stereoselectivity of this reaction are examined and allow us to set out the possibility of a trans hydroboration.
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