Transformations of Methylplatinum(II) Dimers containing Bridging Cyclometallated 1,2-Bis(diphenylphosphino)ethane; X-Ray Crystal Structure of a Sterically Crowded Bis Dimer

DOI: 10.1039/c39830000032

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 32 - 34 (1983)

Update date:2022-07-30

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Authors:

Arnold, Dennis P.

Bennett, Martin A.

McLaughlin, George M.

Robertson, Glen B.

Whittaker, Michael J.

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Article abstract of DOI:10.1039/c39830000032

The methyl group in the 1:1 adduct of methyl iodide with the Pt^I-Pt^I dimer >2 is either bridging or migrating rapidly on the n.m.r. time-scale between the metal atoms; the adduct reacts with methyl-lithiu

Full text of DOI:10.1039/c39830000032

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