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New 2,4,6-substituted 1,3-dioxanes: Synthesis, stereochemistry and thermodynamic data determinations by cis-trans isomers equilibrium

DOI: 10.1515/HC.2005.11.5.389

Source and publish data:

Heterocyclic Communications p. 389 - 394 (2005)

Update date:2022-09-26

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Authors:

Balog, MirelaBalog, Mirela

Ramondenc, YvanRamondenc, Yvan

Oprean, IoanOprean, Ioan

Grosu, IonGrosu, Ion

Ple, GerardPle, Gerard

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Article abstract of DOI:10.1515/HC.2005.11.5.389

The thermodynamic data (A-values) for some substituents located at position 2 of the 1,3-dioxane ring are calculated from the ratio (measured by GC-MS and NMR) of cis and trans isomers of some 2,4,6-substituted-1,3-dioxanes obtained by the condensation reaction of meso 2,4-pentanediol with several aldehydes and ketones. The stereochemistry of these compounds is deduced from high-field NMR experiments.

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Full text of DOI:10.1515/HC.2005.11.5.389

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Download Date | 5/26/15 1:52 AM  
Brought to you by | Purdue University Libraries  
Authenticated  
Download Date | 5/26/15 1:52 AM  
Brought to you by | Purdue University Libraries  
Authenticated  
Download Date | 5/26/15 1:52 AM  
Brought to you by | Purdue University Libraries  
Authenticated  
Download Date | 5/26/15 1:52 AM  
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Products guided by the article

Product name:r-2-benzyl-2,cis-4,cis-6-trimethyl-1,3-dioxane

Cas No:862158-58-5

862158-58-5

R&D Labs maybe for 862158-58-5

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