The Monocation and Monoanion of Re2(μ-Cl)2(μ-dppm)2Cl4 (dppm = Ph2PCH2PPh2). An Unusual Pair of Complexes possessing Metal-Metal Bond Orders of 1.5 that differ in Electronic Configuration

DOI: 10.1039/c39850000114

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 114 - 116 (1985)

Update date:2022-09-26

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Authors:

Dunbar, Kim R.

Powell, Douglas

Walton, Richard A.

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Article abstract of DOI:10.1039/c39850000114

The one-electron oxidation and one-electron reduction of Re2(μ-Cl)2(μ-dppm)2Cl4 (dppm = PH2PCH2PPh2) can be accomplished using NOPF6 and cobaltocene as the oxidant and reductant, respectively, to give paramagnetic ions that possess metal-metal bond orders

Full text of DOI:10.1039/c39850000114

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