The Monocation and Monoanion of Re2(μ-Cl)2(μ-dppm)2Cl4 (dppm = Ph2PCH2PPh2). An Unusual Pair of Complexes possessing Metal-Metal Bond Orders of 1.5 that differ in Electronic Configuration

DOI: 10.1039/c39850000114

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 114 - 116 (1985)

Update date:2022-09-26

Topics:

Authors:

Dunbar, Kim R.

Powell, Douglas

Walton, Richard A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850000114

The one-electron oxidation and one-electron reduction of Re2(μ-Cl)2(μ-dppm)2Cl4 (dppm = PH2PCH2PPh2) can be accomplished using NOPF6 and cobaltocene as the oxidant and reductant, respectively, to give paramagnetic ions that possess metal-metal bond orders

Full text of DOI:10.1039/c39850000114

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{Re₂Cl₆(CH₂(P(C₆H₅)2)2)2}⁽¹⁺⁾*BF₄^(1-)={Re₂Cl₆(CH₂(P(C₆H₅)2)2)2}BF₄

Cas No:96322-62-2

R&D Labs maybe for 96322-62-2

Guangzhou Chemical Reagent Factory

Contact:+86-20-8435 9820 or 8435 7345

Address:Southern Guangzhou, Guangdong, China
Zhejiang Newfine Industry Co.,Ltd.

Contact:+86-573-82262042

Address:No.225,Dongqing Road, garoms@163.com
AllyChem Co., Ltd., Dalian, China（BBChem）

Contact:+86-411-62313318/62313328

Address:No.5 of Jinbin Road, Jinzhou New District, Dalian City, Liaoning Province, P.R.China
Xinjiang Fufeng Biotechnologies Co., Ltd.

Contact:+86-539-7287111

Address:GANQUANPU INDUSTRIAL PARK, ECONOMIC AND TECHNOLOGICAL DEVELOPMENT AREA (TOUTUNHE DISTRICT) OF URUMQI
QINGDAO ON-BILLION INDUSTRAIL CO.,LTD

website:http://www.obn.com.cn

Contact:+86-15005320811 +86-532-80681989

Address:F35 Parkson Mansion No.44-60 Zhongshan Rd.

Relevant to this article

General Synthetic Approach to the Quinolizidine Alkaloids via a <2+3>-Cycloaddition

Doi:10.1039/c39810000940
(1981)
Activation of vinylidenebis(diphenylphosphine) through metal complexation

Doi:10.1021/om00126a013
(1985)
Doi:10.1021/ja01519a048
(1959)
SODIUM 6-METHOXY-(E,E)-3,5-HEXADIENOATE: A USEFUL DIENE IN THE AQUEOUS DIELS-ALDER REACTION

Doi:10.1016/S0040-4039(01)81667-1
(1984)
Peripheral Substitution of Tetraphenyl Porphyrins: Fine-Tuning Self-Assembly for Enhanced Electroluminescence

Doi:10.1002/cplu.201700416
(2018)
Deuterium isotope effects on ³¹P NMR parameters: Hydrogen bonding in a solid urea-phosphoric acid adduct

Doi:10.1039/FT9969205047
(1996)

Article Doi